How To Remove Gunpowder From Skin? Quick Answer

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How long does gunpowder stay on the skin?

Gunshot residue is the consistency of flour and typically only stays on the hands of a living person for 4–6 hours. Wiping the hands on anything, even putting them in and out of pockets can transfer gunshot residue off the hands.

Can you wash off gunpowder?

These cannot be completely removed by normal washing or cleaning, and samples of the particles can be taken from suspects with adhesive collection devices for further investigation. More than 30 years ago scientists working in crime laboratories developed a different means of analyzing gunpowder residue.

What cleans gunpowder residue?

One other home remedy but not really recommended is using washing soda. You can buy it in any drugstore. It has the corrosive properties to remove gunpowder stains or residue.

Does gunpowder stain skin?

Remember that traces of gunpowder residue can be found on clothing or skin, as well as on the surface, for up to 78 hours after firing a firearm.

Is it Still a Viable Form of Physical Evidence?

Gunshot residue is the consistency of flour and lasts only 4–6 hours on a living person’s hands. Wiping hands on anything, including plugging in and out, can transfer gunshot residue.

Can Gsr be washed off? The shooter’s skin and clothing are spattered with these particles. These cannot be completely washed off or removed, so samples of the particles can be taken by suspects with glue collection devices for further investigation.

Does shooting a gun leave residue? Archers’ hands are covered in a cloud of fine particles when their weapons go off, leaving metal fragments in their wake. The Instant Shooter Identification Kit, which provides answers in seconds and is accurate 90% of the time, is a well-known method of checking for bullet residue.

How long does gunpowder stay on your clothes? Remember that up to 78 hours after a firearm has been fired, traces of gunpowder residue can be found on clothing or skin, as well as on the surface.

How are gun residues detected? To determine if a firearm has been used, bullet residue analysis (GSR) is the best method. SEM is commonly used to detect and analyze primer particles containing lead (Pb), barium (Ba), and antimony (Sb) by electrophoretic desorption.

How long does gun residue stay on clothing? In addition to indicating a gun’s discharge, component particles do not indicate which gun was fired. How long have particles been present on a surface? If the GSR is not removed from clothing for five years, the GSR remains the same.

Can gunshot residue be washed off? A first residue of these particles is transferred to the skin and clothing of the person holding the firearm. To collect samples of these particles, adhesive collection devices are used to remove samples from suspects that cannot be completely removed by washing or cleaning.

Is gunshot residue detectable over time? Negative GSR results can also be caused by a long period of time between firing a weapon and collecting the kit. Within a short time after discharge, GSR particles can be removed from hands by rubbing hands on other objects or by washing hands. The presence of GSR is not expected to be detected in an active individual after 6-8 hours.

Is bullet residue testing reliable? When a gun is fired, certain chemicals remain on a person’s skin, clothing, or other nearby surfaces (“gunshot residue”) that can be detected by a wipe test. Test results from GSR tests are considered reliable and should be admitted as evidence in court.

Can you wash away Gsr? All GSR should be removed from hands by washing. o Do not regularly draw blood samples from gunshot wound victims. The presence of GSR indicates that the individual has been exposed to GSR.

Does peeing on hands remove gunpowder? Is it true that peeing on your hands will get rid of gunpowder? A shot residue test is unreliable because urea in the urine reacts with the saltpetre in the gunpowder, rendering it undetectable. Gunshot remnants are removed immediately.

Does gunpowder stain clothes? Getting gunpowder out of clothing can be a challenge. A gunpowder stain can be removed by mixing it with water.

Are bullet marks marks? In most cases, GSR is emitted by a firearm when it is fired. Persons in the immediate vicinity of the weapon can be hit by the gas. GSR kits were designed to collect these particles, and the lab’s Trace Evidence department has the tools and expertise to study them.

How long before the gun residue test comes back? “Gunshot residue testing is done in almost every case where a shooting has occurred,” Burleson said. “The main focus of our research is to develop a method that will contribute to the credibility of gunshot residue evidence in court,” he added. “The new test gives you results in 30 to 40 minutes.”

How can gunpowder residue patterns be identified? Detectives can now use an electrode to quickly dab a suspect’s hands to see if he or she has recently fired a gun. Take samples from suspects’ hands, which are then sent to a lab to determine if gunshot residue is present.

Did Tory Lanez have gun residue on hands?

A prior preliminary hearing also included mention of gunshot residue being reported to have been found on Lanez’s hands, as well as Kelsey’s.

Is it Still a Viable Form of Physical Evidence?

Megan Thee Stallion’s full interview with Gayle King was released on Monday.

In it, Megan looked back on the 2020 shooting that allegedly involved Tory Lanez. “It was one of those moments where it shouldn’t have gotten so crazy,” Megan told Gayle as she recalled the night in question.

After Tory reportedly shot Megan in the foot during the incident, he also allegedly offered her $1 million to shut up.

“He stands over the window and shoots. I didn’t want to move at all. I didn’t want to move too fast. … I was really scared because I’d never been shot at before,” Megan said in the video above around the 4:15 mark. Immediately afterwards, Megan said, Tory apologized and made the alleged offer mentioned above.

“I’ll give you all a million dollars if you don’t say anything,” he reportedly said.

A key aspect of Monday’s interview was a medical report showing Megan still has bullet fragments in her feet from the shooting. Complex reviewed the records, which stated:

“The risks and benefits of surgical treatment have been discussed at length and include, but are not limited to, injury to the arteries, veins and nerves in the region, immobility, pain, pressure sores, infection, joint instability, stiffness, loss of limb function, need for re-operation and death.”

The interview with King marks the first time Megan has discussed filming in a television interview. According to Megan, the night in question began with a party at Kylie Jenner’s house. From there, she ended up in a car with her then-girlfriend Kelsey Harris, as well as Tory Lanez and a member of the driver/safety team. An argument is said to have started, which ultimately inspired Megan to get out of the car. She later expressed regret about getting back in the car after being persuaded.

“The argument in the car is getting worse and I don’t want to be in this car anymore because I can see it’s going crazy,” Megan said. She also recalled being allegedly told “dance, bitch” before the shooting began.

As for her initial interactions with police about the shooting, Megan noted that nationwide incidents of police brutality made her skeptical that responding officers would not escalate the situation further.

“The George Floyd incident had just happened,” she said at the 5:39 mark. “Police will definitely shoot first and ask questions afterwards. So I think there’s a hot gun in the car, I’m bleeding, I’ve been shot. You are about to kill someone. Something bad is about to happen.”

Because of this, Megan explained, she initially told police that she sustained injuries from stepping on glass. “I didn’t want them to kill or shoot any of us,” she said.

Commenting on developments surrounding Tory Lanez since the shooting, Megan said he was “trying to distract from the fact that he committed a crime”. Lanez has pleaded not guilty in connection with the shooting. Megan was also asked by Gayle if she and Tory had ever had an “intimate relationship”, with Megan noting that they had become “close” as friends around that time, initially bonding over the loss of their parents.

“I haven’t had a sexual relationship with Tory,” she said around the 9:41 mark.

See more, including mentioning a July 2020 preserved text from Kelsey to Megan’s security that reads “Tory shot Meg,” above and/or below via CBS Mornings.

This month, a judge found Lanez to have violated a protective order in connection with the Megan case. His bail was also increased in connection with a series of tweets including – as described in this BuzzFeed News report – inaccurate information about the case. A previous preliminary hearing also included mention of gunshot residue reported to have been found on Lanez’s hands as well as Kelsey’s hands. The last point (which had previously been shared with a focus on Kelsey instead of Tory) resurfaced the day Megan’s interview premiered. According to the latest information, a test date is set for this September.

Does gunpowder come out of clothes?

Unfortunately there is no way to remove gunpowder from clothes that is sure not to damage them, as it is simply too tough a stain.

Is it Still a Viable Form of Physical Evidence?

Gunpowder is one of the hardest stains to remove from clothing. The fact that – once it gets on your skin – it’s like a tattoo should give you an idea of ​​what a stubborn stain it is. Washing soda is best: It contains, among other things, the extremely caustic carbolic acid. If you use this mixed with water you can pick off a gunpowder stain.

How long does a gunshot residue test take?

“Gunshot residue tests are done in almost every case where a shooting has taken place,” Burleson said. “The main focus of our research is to develop a method that will help credibility of gunshot residue evidence in court. You can get results with this test in 30 to 40 minutes with the new test.

Is it Still a Viable Form of Physical Evidence?

“When a gun is fired, the gunpowder explodes, creating extremely high-pressure gases that propel the bullet out of the gun’s barrel,” explained Burleson, a graduate student in the Master of Science in Forensic Science program at Sam Houston State University. “Some of the residue from this blast is deposited on the gunman’s hands and the victim’s clothing.” Burleson’s new test, which uses a technology called solid-phase microextraction combined with gas chromatography, focuses on chemical compounds found in this ejected material are present. “If you have a residue particle, no matter how small, it will contain signatures from every element in that powder.”

Does gunpowder contain lead?

Lead is found in bullets as well as the explosive that ignites gunpowder.

Is it Still a Viable Form of Physical Evidence?

Facts matter: Sign up for the free Mother Jones Daily Newsletter. Support our nonprofit reporting. Subscribe to our print magazine.

The most ubiquitous danger at shooting ranges has a lot to do with bullets, but nothing to do with being shot.

It’s all in the lead. A recent report from the National Academy of Sciences found that OSHA standards for lead exposure are too lax to protect military firing range personnel. Repeated exposure to the toxic metal causes a range of health problems, including brain damage, high blood pressure and anemia.

Lead is found in both bullets and the explosive that ignites gunpowder. When a bullet is fired, it gets so hot that the lead actually vaporizes. Range personnel inhale the lead fumes and ingest lead dust, which settles on their bodies and clothing. OSHA sets the allowable level of atmospheric lead at 50 micrograms/meter2, but the report found that military firing ranges often exceed that level, sometimes by orders of magnitude.

The new report also finds OSHA’s recommendation for blood lead levels of 40 µg/dL or less to be too high. This limit has not changed since 1978, but later research has found health problems at blood lead levels as low as 5 µg/dL. Lead is so harmful because it mimics calcium, an ion that plays essential roles throughout the body, from bones to nerve cells. (It’s especially dangerous for children with developing brains, which is why lead paint is heard so much.) The report devotes more than 70 pages to detailing lead’s many toxic effects in nearly every organ in the body, including the brain, blood, and kidneys , heart and reproductive organs.

How can shooting range workers reduce their exposure? The most direct solution is to switch to lead-free ammunition, or at least jacketed bullets, which have a lead core encased in a copper or nylon jacket. Lead has traditionally been favored for its density, but the military has since developed lead-free ammunition that reportedly works just as well.

If OSHA adopts stricter standards, it would be just another step in the long road to recognizing the dangers of lead. In recent decades, the Centers for Disease Control and Prevention has lowered worrisome blood lead levels in children from 60 µg/dL to 25 to 10 to the current 5, and the metal has largely disappeared from gasoline, water pipes, tin cans and paint.

That’s great, but lead is an element, so it doesn’t degrade or become less toxic over time. Old bullets (or paint or gas or other causes) seep into the ground; from there the metal finds its way into the groundwater, into plants and into the bodies of animals. The military has cleaned out about 700 of its firing ranges, and while that doesn’t come cheap, Kevin Drum’s “America’s Really Criminal Element: Lead” convincingly proves that it’s far less expensive than the costs associated with exposure to lead – including violent crime , lower IQs and ADHD.

Either way, the lessons learned from cleaning shooting ranges are relevant, even if you’ve never owned a gun or don’t live near a shooting range. That’s because soil lead is, in fact, just as pervasive a public health hazard as the more publicized lead paint problem. If you live in a city, chances are your house is surrounded by soil with a fairly high lead content. To learn more about the risks you face, read ‘Is there lead in your home?’ – also in the January/February 2013 issue of Mother Jones.

How much gunpowder is in a bullet?

That means each bullet usually only takes 5 grains of powder for loading.

Is it Still a Viable Form of Physical Evidence?

Want to make custom ammo for your next trip to the shooting range? If so, you need to know how much gunpowder you need to make a bullet.

So how many grains of gunpowder is in 1 pound?

A pound of gunpowder has 7,000 grains of powder, no matter what type of powder you use. Measuring the correct amount of gunpowder is critical to ensuring bullet accuracy and effectiveness.

Let’s learn more about gunpowder, grain, and how it all fits together.

What exactly are spherical grains?

A grain is a unit used to measure the weight of a ball. Being a tiny entity, the weight of a grain is almost negligible – only 0.064 grams, in fact! The number of grains in a case is related to the total weight of the bullet.

This is where it gets complicated – bullets are often weighed in grains. But their grain weight doesn’t necessarily mean they contain all of those grains. For example, a 230 grain bullet does NOT contain 230 grains of powder.

Also, the center punch weight only measures the weight of the bullet, not the cartridge that came with it.

What units are grains measured in?

Grains are measured in grams, ounces, and pounds.

Gunpowder weight Number of grains 0.064 grams 1 grain 1 gram 15.43 grains 1 ounce 437.5 grains 1 pound 7,000 grains

Remember that 1 pound of gunpowder contains 7000 grains, whether it’s smokeless or black powder. As long as it weighs 1 pound, each type of powder invariably contains the same number of grains. 1 pound of powder = 458.592 grams.

Since you know how many grains are in a pound, you can also determine the ratio of grains to grams, grains to ounces, and more.

How many bullets can 1 pound of gunpowder make?

The number of bullets per pound of gunpowder depends on the size of the ammunition and the charge of the powder. A powder’s “charge weight” is how much motive power it imparts to a projectile (i.e. bullet), usually expressed as “weight in pounds”. More charge means bigger boom.

But different bullets require different charge weights per charge or per shot to be used safely. That’s why it’s important to decide how big you want the bowls to be. After that, you can make the necessary calculations to know the gunpowder charge in each bullet.

You should also have a reload guide handy before you start loading your own ammo. These books are made by gunpowder makers who know how many grains of powder you should put in different calibers of bullets.

For example, 9mm bullets (some of the most common for self-defense) come in 115, 124, and 147 grain (gr) grades. But none of them hold more than 100 grains of gunpowder! Instead, the most common charge weight is 5. This means that each bullet typically only needs 5 grains of powder to load.

9mm

In the example above of using charges of 5 grains, you could make 1,400 9mm bullets since each only takes 5 grains and 1 pound of gunpowder contains 7,000 grains.

7,000 grains / 5 grains per ball = 1,400 balls.

.223 Remington cartridges

Their source may vary, but most people use charges of around 25 grains.

7,000 grains / 25 grains per bullet = 280 .223 Remington bullets

Remember that each bullet type requires a different type of powder charge.

We recommend the Lyman 50th Edition Ammo Reloading Book, which has a lot of loading information you can use on popular ammo types. It can also help you with powder conversion and is excellent value for money.

Lyman 50th Edition Reloading Handbook Check price

Speer also has a lot of reload data that you can use to reload. Their guides are comprehensive and freely available online.

Alternatively, check gun forums and posts – amateur shooters on a good forum can offer their expertise with a helpful post or two and make sure you’re loading your gun correctly.

Importance of choosing the right shot grains

It’s important to remember to choose the right powder load for your bullet. If you don’t, your bullet may not enter your firearm’s receiver and cause a dud. On the other hand, if you overfill your bullet by filling it with too many grains of gunpowder, you can detonate it too violently, leading to an accident and possible injury.

Heavier bullets usually require more grains of gunpowder, or require larger grains of gunpowder to produce a proper explosion. Lighter bullets require fewer grains of gunpowder on average. However, this can vary dramatically from bullet to bullet depending on their materials, what types of weapons they’re used with, and more.

Bullet Size grains 9mm Luger 5.6 grains .223 25 grains .308 cartridge 45 grains

Again, be sure to use a gunpowder loading guide like the one recommended above to load your bullets carefully and safely, especially if you’re a beginner.

Smaller vs. larger grains

The size of the ball powder grains can also vary. With gunpowder, the smaller the grains, the more surface area is exposed to the priming substance. As a result, they usually burn faster than larger grains.

Of course, ammunition that uses smaller grains for its charge weight will detonate faster and with higher initial velocity from the barrel of a firearm. However, this earlier firing mostly ends before the bullet leaves the barrel of a firearm. Therefore, it does not maintain its speed for so long.

Larger grains are the opposite. Their surfaces are not exposed to explosives like smaller grains, so they take longer to burn through completely on their way down a gun’s barrel. So larger grains might be better when you need to make sure your bullet travels far and accurately without losing speed.

Note, however, that this is not a hard and fast rule, and different types of crops behave differently under fire (no pun intended). Be sure to refer to the loading guide above for specific bullet loads and load weights

Conclusion

Bottom Line: There are 7000 grains per pound of gunpowder. But remember, this doesn’t mean that you can simply divide 7000 by the bullet grain weight to know how many rounds you can fire. Each bullet’s grain weight measures its real weight, but the charge weight determines how many bullets you can make with a pound of gunpowder.

Can you wash your hands with Ajax?

This product cuts grease to get dishes clean and spotless. This product also washes away bacteria on hands (when used as a handsoap, to wash away dirt and bacteria from hands, wash them for 20 seconds under clean running water) and fights odor on dishes.

Is it Still a Viable Form of Physical Evidence?

CVS.com® is not available to customers or patients outside of the United States or US territories. We apologize for the inconvenience.

For US military personnel permanently or temporarily deployed abroad, please contact our customer service team at 1-800-SHOP CVS (1-800-746-7287) if you need assistance with your order.

Where is gunshot residue typically found?

Gunshot residue (GSR) is composed of primer particles that are propelled from the sides and the barrel of a firearm at the moment of discharge. Subsequent to discharge, GSR particles can be detected both on the hand of the shooter and on other nearby surfaces or within a few feet of the sides of the firearm.

Is it Still a Viable Form of Physical Evidence?

Gun Residue (GSR) consists of primer particles that are thrown off the sides and barrel of a firearm at the moment of discharge. Once discharged, GSR particles can be captured on the shooter’s hand as well as other nearby surfaces, or within a few feet of the sides of the firearm.

A typical GSR collection kit contains adhesive pads to collect samples from a person’s hands. The adhesive discs are analyzed directly using scanning electron microscopy coupled with energy-dispersive X-ray analysis (SEM-EDX). The scanning electron microscope allows the size and morphology or shape of the particle to be studied, while the X-ray detector provides elementary data about the particle of interest. The most common elements in gunshot residue are lead, antimony and barium.

Because each of the three key elements (lead, barium, or antimony) can also be found in common environmental particles, it is important for the scientist to consider background particles found on hands in order to interpret the results of a gunshot residue analysis.

How is gunshot residue detected?

A SCANNING ELECTRON MICROSCOPE (SEM) EQUIPPED WITH ENERGY DISPERSIVE X-RAY ANALYSIS CAPABILITY IS USED TO ESTABLISH CRITERIA FOR THE IDENTIFICATION OF GUNSHOT RESIDUE ON THE HAND OF A PERSON FIRING A WEAPON.

Is it Still a Viable Form of Physical Evidence?

abstract

MICROMOMETER-SIZED PARTICLES OF BULLET RESIDUES, COATINGS OR JACKETS ABOVE THE BULLET, AND INGREDIENTS IN THE FUZE REMAIN ON HAND WHEN A PERSON PUSHES A GUN. THESE PARTICLES HAVE A CHARACTERISTIC APPEARANCE UNDER A SEM. COMBINED WITH X-RAY ANALYSIS TO DETERMINE THE METALLIC COMPOSITION OF THE PARTICLES, THE SEM CAN NOT ONLY INDICATE WHETHER A WEAPON HAS BEEN FIRED BUT ALSO THE POSSIBLE TYPE OF AMMUNITION USED. THIS STUDY ANALYZES THE RESULTS OF SEVERAL HUNDRED SMALL ARMS RIFLES TO DEVELOP CRITERIA FOR IDENTIFYING THESE PARTICLE PATTERNS. THE RESULTS ARE PRESENTED AS A NARRATIVE AND A SERIES OF TABLES SHOWING THE BULLET COMPOSITION, BULLET JACKET OR COATING AND PRIMER FOR THE MOST COMMON HANDGUN TYPES. (This magazine article is a summary of a complete report that contains the complete test results and which was written for use as a training instructions.) Photographs illustrate various particle patterns, while a diagram shows the ratio between the number of spheroidal particles and the mouth speed. CHARACTERIZATION OF GUN RESISTANCE HAS BEEN PROVIDED APPROPRIATE FOR SUCCESSFUL ANALYSIS OF ACTUAL CASES. (A SECOND REPORT DISCUSSES INDUSTRIAL RESIDUES THAT MAY BE CONFUSED WITH SHUNT RESIDUES – SEE NCJ 57028.) REFERENCES PENDING. (GLR)

How long does a GSR test last?

“Gunshot residue tests are done in almost every case where a shooting has taken place,” Burleson said. “The main focus of our research is to develop a method that will help credibility of gunshot residue evidence in court. You can get results with this test in 30 to 40 minutes with the new test.

Is it Still a Viable Form of Physical Evidence?

“When a gun is fired, the gunpowder explodes, creating extremely high-pressure gases that propel the bullet out of the gun’s barrel,” explained Burleson, a graduate student in the Master of Science in Forensic Science program at Sam Houston State University. “Some of the residue from this blast is deposited on the gunman’s hands and the victim’s clothing.” Burleson’s new test, which uses a technology called solid-phase microextraction combined with gas chromatography, focuses on chemical compounds found in this ejected material are present. “If you have a residue particle, no matter how small, it will contain signatures from every element in that powder.”

How is gunshot residue detected?

A SCANNING ELECTRON MICROSCOPE (SEM) EQUIPPED WITH ENERGY DISPERSIVE X-RAY ANALYSIS CAPABILITY IS USED TO ESTABLISH CRITERIA FOR THE IDENTIFICATION OF GUNSHOT RESIDUE ON THE HAND OF A PERSON FIRING A WEAPON.

Is it Still a Viable Form of Physical Evidence?

abstract

MICROMOMETER-SIZED PARTICLES OF BULLET RESIDUES, COATINGS OR JACKETS ABOVE THE BULLET, AND INGREDIENTS IN THE FUZE REMAIN ON HAND WHEN A PERSON PUSHES A GUN. THESE PARTICLES HAVE A CHARACTERISTIC APPEARANCE UNDER A SEM. COMBINED WITH X-RAY ANALYSIS TO DETERMINE THE METALLIC COMPOSITION OF THE PARTICLES, THE SEM CAN NOT ONLY INDICATE WHETHER A WEAPON HAS BEEN FIRED BUT ALSO THE POSSIBLE TYPE OF AMMUNITION USED. THIS STUDY ANALYZES THE RESULTS OF SEVERAL HUNDRED SMALL ARMS RIFLES TO DEVELOP CRITERIA FOR IDENTIFYING THESE PARTICLE PATTERNS. THE RESULTS ARE PRESENTED AS A NARRATIVE AND A SERIES OF TABLES SHOWING THE BULLET COMPOSITION, BULLET JACKET OR COATING AND PRIMER FOR THE MOST COMMON HANDGUN TYPES. (This magazine article is a summary of a complete report that contains the complete test results and which was written for use as a training instructions.) Photographs illustrate various particle patterns, while a diagram shows the ratio between the number of spheroidal particles and the mouth speed. CHARACTERIZATION OF GUN RESISTANCE HAS BEEN PROVIDED APPROPRIATE FOR SUCCESSFUL ANALYSIS OF ACTUAL CASES. (A SECOND REPORT DISCUSSES INDUSTRIAL RESIDUES THAT MAY BE CONFUSED WITH SHUNT RESIDUES – SEE NCJ 57028.) REFERENCES PENDING. (GLR)

Shooters, WASH YOURSELF! Lead Removal Wipes and Soap for Gun Owners / Shooters (D-Lead)

Shooters, WASH YOURSELF! Lead Removal Wipes and Soap for Gun Owners / Shooters (D-Lead)
Shooters, WASH YOURSELF! Lead Removal Wipes and Soap for Gun Owners / Shooters (D-Lead)


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Gunshot residue

Bullet residue from a pistol shot

Gunshot Residue (GSR), also known as cartridge discharge remnant (CDR), “gun fire remnant” (GFR), or firearm discharge remnant (FDR), consists of all the particles ejected from the muzzle of a gun after the discharge of a bullet. It consists mainly of burned and unburned particles of detonation, the propellant (gunpowder) and vaporized lead. The act of firing a bullet triggers a very violent explosive reaction contained within the gun’s barrel, which can cause the bullet, barrel, or cartridge to rupture. This means that shot residue may also include metal fragments from the cartridge case, bullet casing, and any other dirt or debris contained in the barrel that may have become loose.

A graphical representation of the GSR left on a target when fired at from varying ranges.

Law enforcement investigators will wipe people’s hands to look for gunshot residue if they are suspected of having fired a firearm themselves or were in close contact with a firearm at the time of delivery. Gunshot remnants don’t travel very far because the particles created are small in size and mass, which means they lack momentum. Depending on the type of firearm and ammunition used, it will usually not travel more than 0.9 to 1.5 meters (3 to 5 ft) from the gun’s muzzle.

history [edit]

Before using the scanning electron microscope, hot paraffin wax was used to take an impression of the suspect’s hand. The cast was then sprayed with a reagent that gave a nitro compound stain from the partially burned and unburned propellant particles. This approach, introduced in 1933 by Teodoro Gonzalez of the Mexico City Police Laboratory, is called the dermal nitrate or paraffin test and is no longer used in casework.

In 1971, John Boehm presented some micrographs of bullet residue found when examining bullet holes with a scanning electron microscope. If the scanning electron microscope is equipped with an energy-dispersive X-ray spectroscopy detector, the chemical elements contained in such particles, mainly lead, antimony and barium, can be identified.

In 1979, Wolten et al. proposed a classification of gunshot residue based on composition, morphology, and size. Four compositions were considered characteristic:

lead, antimony and barium

barium, calcium and silicon

antimony

barium

The authors proposed some rules about chemical elements that might also be present in these particles.

Wallace and McQuillan published a new classification of gunshot residue particles in 1984. They referred to particles as unique particles containing lead, antimony and barium or containing antimony and barium. Wallace and McQuillan also claimed that these particles could only contain a few chemical elements.

Current practice[edit]

In the latest ASTM Standard Guide for GSR analysis by Scanning Electron Microscopy/Energy Dispersive X-ray Spectrometry (SEM-EDX), lead, antimony and barium-containing particles are considered in compliance with some rules regarding the morphology and the presence of other elements characteristic of GSR. The most definitive way to determine whether a particle is characteristic of or consistent with GSR is its elemental profile. One approach to identifying particles characteristic or consistent with GSR is to compare the elemental profile of the recovered particles to that collected from case-specific known source items such as the recovered weapon, cartridge cases, or victim-related items whenever necessary . This approach was referred to as “case-by-case” by Romolo and Margot in an article published in 2001. In 2010, Dalby et al. published the most recent review on the subject and concluded that adopting a case-by-case approach to GSR analysis must be considered preferable, in agreement with Romolo and Margot.

Given similar particles originating from external sources, both Mosher et al. (1998) aima et al. (2012) presented evidence of pyrotechnic particles that can be misidentified as GSR. Both publications emphasize that certain exclusion markers and references to the general population of collected particles can help the expert to designate GSR-like particles as firework origin.

Particle analysis by a scanning electron microscope equipped with an energy dispersive X-ray spectroscopy detector is the most powerful forensic tool that investigators can use to determine an individual’s proximity to a discharged firearm or contact with a GSR exposed surface (firearm, spent cartridge case, etc.). ) to determine target hole). Test accuracy requires procedures that avoid secondary transfer of gunshot residue from police officers to the person or object being tested and contamination in the laboratory.

The two main groups of specialists currently involved in gunshot residue analysis are the Scientific Working Group on Gunshot Residue (SWGGSR) based in the US and the ENFSI EWG Firearms/GSR Working Group based in Europe.

Results [edit]

A positive result for smoke residue in the SEM-EDX analysis can mean many things. Mainly, this suggests that the sampled person was either in the vicinity of a firearm when it was fired, was handling a firearm after the shot was fired, or was touching something that was in the vicinity of the firearm when it was fired. (For example, when a person comes to the aid of a gunshot victim, some gunshot residue may be carried over from the victim.)

A negative result may mean that the person was not near the gun when it was fired, or that they were close but not close enough for bullet debris to land on it, or it may mean that the bullet debris deposited on it have worn out. Gunshot residue has the consistency of flour and typically stays on a living person’s hands for only 4–6 hours. Wiping your hands on anything, even plugging it in and out, can transfer gunshot residue from your hands. Victims don’t always get gunshot residue; Even suicide victims can test negative for gunshot residue.

Matching gunshot residue to a specific source[edit]

If the ammunition used was in some way specifically marked by special elements, it is possible to know the cartridge that was used to make the remnants of the shot. Inferences about the source of gunshot residue can be based on examining the particles found on a suspect and the population of particles found on the victim, in the firearm, or in the cartridge case, as suggested in the ASTM Standard Guide for Gunshot Residue Analysis by scanning electron microscopy/energy dispersive X-ray spectrometry. Advanced analytical techniques such as ion beam analysis (IBA), performed after scanning electron microscopy, can provide further information that allows inferring the source of the gunshot residue particles. Christopher et al. demonstrated how the grouping behavior of different makes of ammunition can be determined using multivariate analysis. Bullets can be reassigned to a weapon using comparative ballistics.

Organic gunshot residue [ edit ]

Organic grist residue can be analyzed by analytical techniques such as chromatography, capillary electrophoresis and mass spectrometry.

See also[edit]

Recoil, material drawn down the barrel of a firearm after discharge

References[ edit ]

ASTM E1588-10e1, Standard Guide for GSR Analysis by Scanning Electron Microscopy/Energy Dispersive X-ray Spectrometry, American Society for Testing and Materials, West Conshohocken, PA, 2010.

E. Böhm, Application of the SEM in forensic medicine, Scanning Electron Microscopy (1971) 553-560.

Christopher M, Warmenhoven J, Romolo FS, Donghi M, Webb R, Jeynes C, Ward NI, A new quantitative method for the analysis of gunshot residue by ion beam analysis. Analyst, 2013, 138, 4649.

O. Dalby, D. Butler, J.W. Birkett, Analysis of gunshot residue and associated materials – a review, J. Forens. Science. 55 (2010) 924-943.

Grima M, Butler M, Hanson R, Mohameden A, Fireworks as sources of gunshot residue-like particles, Science and Justice 52 (1) (2012) 49-57.

H.H. Meng, B. Caddy, Gunshot Residue Analysis – Review, J. Forens. Science. 42 (1997) 553-570.

P.V. Mosher, M.J. McVicar, E.D. Randall, E.H. Sild, Bullet-Residue-Like Particles Produced by Fireworks, Journal of the Canadian Society of Forens. Science. 31 (3) (1998) 157-168.

F.S. Romolo, ME Christopher, M Donghi, L Ripani, C Jeynes, R P Webb, N.I. Ward, Integrated ion beam analysis (IBA) in the characterization of bullet residue (GSR). Forensic Science. international 231 (2013), 219-228.

F.S. Romolo. Advances in gunshot residue analysis. In Emerging Technologies for the analysis of forensic traces, edited by Simona Francese, Springer Publishing Company, pages 183-202, ISBN 978-3-030-20541-6.

AJ Schwoeble, D.L. Exline, Current Methods in Forensic Gunshot Residue Analysis, (2000) CRC Press LLC.

JS Wallace, J. McQuillan, Discharge residues from cartridge-powered industrial tools, J. Forens. Science. society 24 (1984) 495-508.

JS Wallace, Chemical Analysis of Firearms, Ammunition and Residues, (2008) CRC Press LLC.

GM Wolten, RS Nesbitt, A.R. Calloway, GL Loper, PF Jones, Particle analysis for the detection of gunshot residue. I: Scanning electron microscopy/energy dispersive X-ray characterization of hand deposits upon firing, J. Forens. Science. 24 (1979) 409-422.

GM Wolten, RS Nesbitt, A.R. Calloway, GL Loper, Particle Analysis for Detecting Gunshot Residue. II: Occupational and Environmental Particles, J. Forens. Science. 24 (1979) 423-430.

GM Wolten, RS Nesbitt, A.R. Calloway, Particle analysis to detect traces of smoke. III: the case file, J. Forens. Science. 24 (1979) 864-869.

Is it Still a Viable Form of Physical Evidence?

Checking for shot residues:

Is it still a viable form of physical evidence?

Compiled by Don Penven

Gun Shot Residue, or simply GSR, is a means of testing for the presence of certain materials on a subject’s hands and clothing in the hope of determining that that person may have fired a firearm. The concept is old and goes back many years. Advances in testing technology make this test much more specific than it was about 30-40 years ago.

The chemistry of gunpowder

Most historians agree that the ancient Chinese discovered what we call gunpowder. During the 9th century, Taoist monks (alchemists) searching for an elixir of immortality stumbled upon the basic formula for black powder – a mixture of saltpetre (potassium nitrate), charcoal and sulfur. Later versions of gunpowder contain the same basic ingredients, but the general chemistry evolved to include modifications that produced “smokeless gunpowder”, cordite, which eliminated the sulphur. Other advances added materials such as nitrocellulose (guncotton) and glyceryl trinitrate (nitroglycerin).

Gunpowder, regardless of formulation, has a specific purpose: to produce carbon oxides; especially carbon dioxide. The rapid generation of this gas is the motive force that pushes a projectile (missile) down the barrel and further toward its intended target.

What is GSR?

Gunshot residue contains burned particles (potassium nitrite) and some unburned particles (potassium nitrate), and for decades detectives collected these particles by applying melted paraffin wax to a subject’s hands. After removing the wax cast, a reagent containing diphenylamine and sulfuric acid was applied to the cast. The development of bruising was an indication of the presence of nitrates.

But by the 1970s, the courts were taking the position that the presence of nitrates in the environment was a common occurrence and the dermal nitrate test was no longer a valid means of determining that the person had fired a gun.

primer residues

When a gun is fired, the remnants—small particles created during gunpowder explosions—are ejected from the rear of the gun and the muzzle. These particles fly onto the skin and clothing of the person holding the gun. They contain elements resulting from the decomposition of the propellant and primer, as well as the bullet (which usually contains a lot of lead), the bullet coating or casing, cartridge components, and previous residue in the barrel. Characteristic elements are antimony (Sb), lead (Pb), barium (Ba) and for special types of ammunition titanium (Ti) and zinc (Zn). These cannot be completely removed by normal washing or cleaning, and samples of the particles can be taken from suspects using glue collection devices for further investigation.

GSR particles

More than 30 years ago, scientists in crime labs developed a different method for analyzing gunpowder residue. They turned to the components of the primers in most US-made ammunition. The main components sought were barium, antimony and lead. After the investigator swabbed the subject’s hands with a 5% nitric acid solution, these swabs were submitted to the crime lab for atomic absorption analysis.

As science improved, a new, more reliable test method emerged: scanning electron microscopy (SEM). Test samples for SEM are collected with contamination-free tape strips. The apparatus used in this test allows the examiner to actually see the collected microscopic samples and get an analysis of the particles present.

cross contamination

“We have met the enemy and he is us.” Pogo

Cross-contamination occurs when GSR is introduced from a source other than the suspect firing a gun.

When the lab techs find GSR, it can come from anywhere. The police believe that you fired the murder weapon unless you just left the shooting range. This argument carries a lot of weight if you live in a society where guns are rare, like Singapore or Japan. If you live anywhere else in the world, including the United States, this argument means nothing.

GSR lasts almost forever. It can land on anything and stay there indefinitely. Since so many people in this country shoot guns and things in their lives are covered with GSR, if a person comes into contact with these people or anything they have touched, they will become covered with GSR. When tested, the person will test positive for GSR. It’s human nature to see what you want to see, and the police want to see what will solve the crime.

“The ability to contaminate is why there are so few conclusions to be drawn with gunshot residue,” said Marc S. Taylor, a gunpowder residue expert from California who has testified nationally for both prosecutors and defense attorneys. You should never claim that gunshot residue shows someone fired a gun.”

After a highly controversial case involving GSR, Baltimore internal police documents show contamination was a recurring problem. Despite this and prosecution scrutiny, the department continues to use gunshot residue in hundreds of cases each year. On the other hand, the FBI lab stopped offering GSR tests.

Special Agent Ann Todd, spokeswoman for the FBI lab, said the change was communicated to FBI field offices electronically on March 15, 2006, although it was not widely disseminated.

Todd said the FBI stopped analyzing gunshot residue because of a shift in priorities, not a lack of confidence in the science.

The lab has been doing the analysis for decades, but in recent years it has received fewer than 10 requests a year, she said. The agency decided its resources would be better deployed in “areas directly related to counterterrorism,” she said.

What to do if the GSR test is positive?

Steven Howard writes in Champion, A Magazine For Defense Lawyers:

Get a particle count. Get it during the discovery phase. If the number is 2000+ on the face, hands and other areas, your client is in trouble. Is the count 20 or less? A person can get this by coming into contact with the police or other people.

Request a breakdown of the arrears. If all three elements are not included, it may not be GSR. Even if all three are present, if the iron is high, it could be pad residue and not GSR at all. Also, some .22 rimfire ammunition does not contain all three elements (Pb, Sb, and Ba). If the police claim your client is the shooter because the GSR test contains the three elements, but the ammunition used in the crime does not contain all three, then “Houston, we have a problem!”

Request photos from the GSR. If the particles are not spherical, this can also be evidence that the residue comes from brake pads and is therefore not GSR.

Have police officers taken steps to prevent cross contamination? Did you wash your hands? Did they clean their cars? Did they bag the suspect’s hands with a sandwich bag and a rubber band? Police in the UK have been sacking hands since the 1940s. Few police departments in this country ever capture the hands of a suspect. Police officers should simply slip a clean evidence bag over the suspect’s hands and secure it with a rubber band or, even better, a “flex cuff”. I realize that this is really high tech, but I really believe that the police in this country can handle this level of technology. Some police departments are now saying, “If you don’t bag them, we won’t test them.”

Using GSR will face many legal challenges over time. It is still a widely accepted evidence-gathering procedure. It is therefore important that all possible means of avoiding cross-contamination are implemented.

References:

Steven Howard, Gunshot Residue and Cross Contamination: An Introductory Lesson, Right To Counsel Newsletter, http://www.civilrighttocounsel.org/news/newsletter/. January 12, 2011

Baltimore Sun article by Julie Bykowicz, “FBI Scraps GSR Tests”, http://www.nacdl.org/public.nsf/UNID/D91C065694E5CE308525717E00770439?OpenDocument, 12 January 2011

About the author

Don Penven has over 35 years of direct and indirect law enforcement experience. He currently serves as a technical support representative and technical writer for Sirchie Finger Print Labs. He maintains the blog: www.CSITECHBLOG.com and can be reached at [email protected]

Article submitted by the author

Article posted: March 1, 2013

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